Apart from some of the great recordings already mentioned I guess I have to throw these in as well:
Bauhaus - Press The Eject
Throwing Muses - The Curse
Jazz Butcher - Hamburg
Soft Boys - Live At The Portland Arms
Robyn Hithccock - Storefront Hitchcock
... although I guess part of me always prefers the purity of the less official and less potentially repaired/overdubbed, re-ordered or 'edited to fit' aspect of the bootleg recording ... but then we could be here all week!